Cover Feature: Elucidating the Sectioning Fragmentation Mechanism in Silica‐Supported Olefin Polymerization Catalysts with Laboratory‐Based X‐Ray and Electron Microscopy (ChemCatChem 21/2022)

نویسندگان

چکیده

The Cover Feature shows an artistic interpretation of a supported polymerization catalyst particle that is fragmenting during ethylene polymerization. In their Research Article, F. Meirer, B. M. Weckhuysen and co-workers used high resolution X-ray electron microscopy to elucidate the origins sectioning fragmentation mechanism in two different silica-supported olefin catalysts at single level. occurrence was shown be favoured by low degree macroporosity silica granulates constituting support, accessibility interior reaction onset, as well fast kinetics. More information can found Article co-workers.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Modelling the catalyst fragmentation pattern in relation to molecular properties and particle overheating in olefin polymerization

A two-dimensional single particle finite element model was used to examine the effects of particle fragmental pattern on the average molecular weights, polymerization rate and particle overheating in heterogeneous Ziegler-Natta olefin polymerization. A two-site catalyst kinetic mechanism was employed together with a dynamic two-dimensional molecular species in diffusion-reaction equation. The i...

متن کامل

Group 3 metal catalysts for ethylene and -olefin polymerization

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 397

متن کامل

modelling the catalyst fragmentation pattern in relation to molecular properties and particle overheating in olefin polymerization

a two-dimensional single particle finite element model was used to examine the effects of particle fragmental pattern on the average molecular weights, polymerization rate and particle overheating in heterogeneous ziegler-natta olefin polymerization. a two-site catalyst kinetic mechanism was employed together with a dynamic two-dimensional molecular species in diffusion-reaction equation. the i...

متن کامل

Uniform serial sectioning for transmission electron microscopy.

Kristen M. Harris,1,2,3 Elizabeth Perry,2 Jennifer Bourne,1,2 Marcia Feinberg,3 Linnaea Ostroff,3 and Jamie Hurlburt2,3 1Section of Neurobiology and Center for Learning and Memory, University of Texas at Austin, Austin, Texas 78712, 2Department of Neurology, Synapses, and Cognitive Neuroscience Center, Medical College of Georgia, Augusta, Georgia 30912, 3Program in Neuroscience and Biology Depa...

متن کامل

Surface science of single-site heterogeneous olefin polymerization catalysts.

This article reviews the surface science of the heterogeneous olefin polymerization catalysts. The specific focus is on how to prepare and characterize stereochemically specific heterogeneous model catalysts for the Ziegler-Natta polymerization. Under clean, ultra-high vacuum conditions, low-energy electron irradiation during the chemical vapor deposition of model Ziegler-Natta catalysts can be...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Chemcatchem

سال: 2022

ISSN: ['1867-3899', '1867-3880']

DOI: https://doi.org/10.1002/cctc.202201198